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Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH
引用本文:郑鹏武 段学民 王伟 王晓季 郭玉萍 涂其冬. Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH[J]. 中国化学, 2006, 24(6): 825-826. DOI: 10.1002/cjoc.200690157
作者姓名:郑鹏武 段学民 王伟 王晓季 郭玉萍 涂其冬
作者单位:[1]School of Pharmacy, Jiangxi Science and Technology Normal University, Nanchang, Jiangxi 330013, China [2]School of Chemical Engineering, Anshan University of Science and Technology, Anshan, Liaoning 114044, China
基金项目:Project supported by the Science Funds of the Education 0ffice of Jiangxi, China (No. [2006]246).
摘    要:Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl3·6H2O or Fe/BiCl3 system in H2O/ethanol (2 : 1, Ⅴ :Ⅴ) at room temperature. Fifteen azides with different functional groups were well reduced to the corresponding amines in excellent yields.

关 键 词:叠氮化物 还原 胺 氨基化合物 Fe/AlCl3体系 Fe/BiCl3体系
收稿时间:2005-07-11
修稿时间:2005-07-112006-02-09

Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH
ZHENG Peng-Wu,DUAN Xue-Min,WANG Wei,WANG Xiao-Ji,GUO Yu-Ping,TU Qi-Dong. Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH[J]. Chinese Journal of Chemistry, 2006, 24(6): 825-826. DOI: 10.1002/cjoc.200690157
Authors:ZHENG Peng-Wu  DUAN Xue-Min  WANG Wei  WANG Xiao-Ji  GUO Yu-Ping  TU Qi-Dong
Abstract:Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl3·6H2O or Fe/BiCl3 system in H2O/ethanol (2:1, V:V) at room temperature. Fifteen azides with different functional groups were well reduced to the corresponding amines in excellent yields.
Keywords:azide   reduction   amine   amide
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