Abstract: | Structural effects: disordering, twinning, polymorphism, and morphotropism due to substitution of halide atoms are considered
using the results of X-ray diffraction analysis of 18 olefinic π-complexes of Cu(I). These effects are associated with the
heterodesmic character of compounds, in particular, with weak interactions such as lengthened coordination bonds and hydrogen
contacts.
Ukrainian State Wood Technology Institute. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 1, pp. 98–107, January–February, 1998. |