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Composition of 2-(3,5-dibromo-2-pyridylazo) diethylaminophenol chelates by liquid chromatography
Authors:Y Zhao
Institution:(1) Department of Environmental Engineering, North China Institute of Electric Power, Baoding, Hebei, People's Republic of China
Abstract:Summary The composition of 3,5-diBr-PADAP metal chelates was determined by liquid chromatography employing appropriate eluents and non-polar bonded stationary phase. The metal-to-ligand ratios were 1ratio2, 1ratio2 and 1ratio2 for Cu(II), Co(III) and Cr(III) respectively, and the V(V)-to-ligand ratio found to be 1ratio1ratio1 in V(V)-3,5-diBr-PADAP-H2O2 in the presence of H2O2. The results are in agreement with literature data.
Keywords:Column liquid chromatography  Composition of chelates  3  5-diBr-PADAP
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