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Modulation of the optical rotation of polarized light by some terpenes depending on solvents properties |
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| Authors: | G. G. Midyana R. G. Makitra E. Ya. Pal’chikova |
| Affiliation: | 1. Physical Chemistry of Fossil Fuels Department, L.M. Litvinenko Institute of Physical Organic and Coal Chemistry, Ukraine National Academy of Sciences, ul. Nauchnaya 3a, Lviv, 79060, Ukraine 2. Institute of Geology and Geochemistry of Fossil Fuels, Ukraine National Academy of Sciences, Lviv, Ukraine |
| Abstract: | The data on the medium effect on the angle of polarized light rotation by optically active substances have been generalized by using the multiparametric linear free energy equations. It has been stated that along with the solvent polarity and polarizability, the specific solvation of the substrate is significant. |
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