Poly(vinyl chloride) reactions with sodium and potassium derivatives of heteroaromatic and aromatic NH- and SH-acids in aprotic solvents |
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| Authors: | N. S. Shaglaeva M. G. Voronkov V. V. Bayandin R. G. Sultangareev G. F. Prozorova K. A. Abzaeva E. A. Orkhokova |
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| Affiliation: | 1. Irkutsk State Technical University, ul. Lermontova 83, Irkutsk, 664074, Russia
2. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
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| Abstract: | The observed featured and regularities of nucleophilic substitution of chlorine in poly(vinyl chloride) upon its reaction with sodium and potassium derivatives of pyrazole, 3,5-dimethylpyrazole, and 2-thiobenzimidazole, and with sodium thiophenolate have been understood in the frame of hard and soft acids and bases theory. |
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