Fabrication of superhydrophobic surface from a supramolecular organosilane with quadruple hydrogen bonding |
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Authors: | Han Joong Tark Lee Dae Ho Ryu Chang Yeol Cho Kilwon |
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Affiliation: | Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, Korea. |
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Abstract: | A supramolecular organosilane, 2-(3-(triethoxysilyl)propylaminocarbonylamino)-6-methyl-4[1H]pyrimidinone comprising quadruple hydrogen bonds has been synthesized in one step from commercially available starting materials. The synthesized supramolecular organosilane can be stabilized and phase-separated by dimerization via the linear array of quadruple hydrogen bonds in solution. This property of the supramolecular organosilane has been exploited to fabricate structuring materials having a superhydrophobic surface property. We have successfully generated the interconnected granular structure with adequate roughness for superhydrophobicity via sol-gel process. |
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