Paired electrosynthesis of cyanoacetic acid |
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| Authors: | Batanero Belen Barba Fructuoso Sánchez-Sánchez Carlos M Aldaz Antonio |
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| Institution: | Department of Organic Chemistry, University of Alcalá, 28871 Alcalá de Henares, Madrid, Spain. |
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| Abstract: | Cyanoacetic acid is formed by cathodic reduction of CO(2) and anodic oxidation of the tetraalkylammonium salt anion; the process is conduced in acetonitrile using a divided cell with a medium porosity glass-frit diaphragm. A mechanism for this paired electrochemical reaction is proposed. |
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