Nuclear magnetic shielding and chirality IV. The odd and even character of the shielding response to a chiral potential |
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Authors: | Sears Devin N Jameson Cynthia J Harris Robert A |
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Affiliation: | Department of Chemistry M/C-111, University of Illinois at Chicago, Chicago, Illinois 60607-7061, USA. |
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Abstract: | We investigate the odd and even character of the shielding response in a chiral molecule (modeled by a Ne8 helix) when subjected to a chiral potential. We establish that the diastereomeric splittings are a measure of odd powers of Vodd. Implications for diastereomeric, splittings of Xe in handed cages with handed tethers are discussed. |
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