1,1,1-Trimethyl-3,3,3-trichlorodisiloxane as a source and a trapping agent for silanones |
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| Authors: | T L Krasnova E A Chernyshev A P Sergeev |
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| Institution: | (1) M. V Lomonosov Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571 Moscow, Russian Federation |
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| Abstract: | The pyrolysis of 1,1,1-trimethyl-3,3,3-trichlorodisiloxane (1) was studied and its mechanism involving the formation of dichloro- and dimethylsilanones was proposed. The composition of the condensate from the co-pyrolysis of siloxane i and hexamethyldisiloxane indicated that under the pyrolysis conditions the simplest siloxanes can be both the sources and the trapping agents of silanones.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1299–1300, May, 1996. |
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| Keywords: | silanones intermediates siloxanes pyrolysis |
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