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Ein neues Oxotantalat mit bronzeähnlicher Kristallstruktur: Ba4CoTa10O30
Authors:Bernd Jasper-Tönnies  Hanskarl Müller-Buschbaum
Affiliation:(1) Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300 Kiel, Bundesrepublik Deutschland
Abstract:Solide state reactions lead to the hitherto unknown compound Ba4CoTa10O30. X-ray single crystal work (space group C2v14-Amm2,a=3.905,b=10.203 andc=14.954 Å) shows, that the octahedron network of Ba4CoTa10O30 is conform to the Na2Nb12O30 F2-Type. On the other hand the occupation of the tunnels is related to the bronze-structure. The different structure types are discussed.
Keywords:Barium  Cobalt  Tantalum  Oxygen  X-Ray-structure
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