| Synthesis and Crystal Structure of a Ruthenium（Ⅱ） Compound of Dinitrogen |
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| 引用本文： | KAN Jian ZHANG Li-Yi WEN Hui-Min SHI Lin-Xi CHEN Zhong-Ning②.Synthesis and Crystal Structure of a Ruthenium（Ⅱ） Compound of Dinitrogen[J].结构化学,2008,27(10):1167-1170. |
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| 作者姓名： | KAN Jian ZHANG Li-Yi WEN Hui-Min SHI Lin-Xi CHEN Zhong-Ning② |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences |
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| 基金项目： | This work was supported by NSF of Fujian Province （No. E0420002） |
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| 摘 要： | The title compound Ru（bph）（PPh3）2（N2）]·（PF6）·1.5CH2Cl2 （bph = N-（benzoyl）- N＇-（picolinylidene）-hydrazine） has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P21/n with a = 13.5201（6）, b = 15.5078（6）, c = 25.0656（13） A, β= 100.257（3）°, C50.50H43Cl3F6N5OP3Ru, Mr= 1150.23, V= 5171.4（4） A3, Z = 4, F（000） = 2332, Dc = 1.477 g/cm^3 and ,μ（MoKa） = 0.615 mm^-1. The structure was refined to R = 0.0524 and wR = 0.1398 for 8060 observed reflections （I 〉 2σ（I））. The Ru-N2 and N-N bond distances are 1.919（4） and 1.133（5）A, respectively.
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| 关 键 词： | 四氧化二氮 钌 化合物 晶体结构 |
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