Advanced electrochemical performances of Li4Ti5O12/Ag prepared by a facile synthesis route |
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Authors: | Hao Ge Li Chen Shen Lin Xicheng Shi Xi-Ming Song |
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Institution: | 1. Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China 2. Research Institute of Chemical Defense, Beijing, 100083, People’s Republic of China
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Abstract: | Spinel Li4Ti5O12 coated by highly dispersed nanosized Ag particles was synthesized via a facile and effective ultrasonic-assisted method in this paper. X-ray diffraction (XRD) results indicated that Ag was not doped into the lattice of spinel Li4Ti5O12. The as-synthesized Li4Ti5O12/Ag exhibited enhanced electronic conductivity and excellent electrochemical performances. Its electronic conductivity was increased about four times compared to that of the pristine Li4Ti5O12. Even at 10 C rate, the as-synthesized Li4Ti5O12/Ag could keep 86.5 % of the reversible capacity at 1 C rate and its reversible capacity was higher than 140 mAhg?1 whereas those were 75.3 % and 118 mAhg?1 for the pristine Li4Ti5O12. |
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