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A new optical and electrochemical sensor for fluoride ion based on the functionalized boron-dipyrromethene dye with tetrathiafulvalene moiety
Authors:Jing XiongLei Sun  Ya LiaoGao-Nan Li  Jing-Lin Zuo  Xiao-Zeng You
Institution:State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, People’s Republic of China
Abstract:A new tetrathiafulvalene (TTF) derivative with the boron-dipyrromethene (BODIPY) moiety shows selectively optical and electrochemical sensing for fluoride ion. The mechanism of anion recognition has been investigated by 1H NMR titration and DFT calculations. The results show that the receptor with redox active TTF moiety and fluorescent BODIPY subunits may be useful as sensors for detecting and sensing fluoride ion.
Keywords:Tetrathiafulvalene  Boron-dipyrromethene  Anions sensing  DFT calculations
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