Synthesis of an insulated molecular wire by click polymerization |
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Authors: | Terao Jun Kimura Kazuya Seki Shu Fujihara Tetsuaki Tsuji Yasushi |
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Institution: | Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. terao@scl.kyoto-u.ac.jp |
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Abstract: | We developed a new method for the synthesis of an organic-soluble insulated molecular wire (IMW) with permethylated cyclodextrin (PMCD); this method involves click polymerization of linked 2]rotaxane containing azide and alkynyl groups at both ends of a π-conjugated guest. |
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