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Chemical Research Faculties: An International Directory : Edited by G.L. Pollock. The American Chemical Society, Washington, 1984, xxxv + ca. 530 pages. US $129.95 (U.S.A. and Canada); US $155.95 (elsewhere). ISBN 0-8412-0817-4.
Authors:Colin Eaborn
Institution:

School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain

Abstract:Heterobinuclear complexes of formula LMCl2(pz)M′(tfb)] (M = Ru, L = p-cymene, M′ = Rh; M = Ir, L = C5Me5, M′ = Rh; M = Rh, L = C5Me5, M′ = Ir) and (C5Me5)IrCl(pz)2Rh(tfb)] (tfb = tetrafluorobenzo5.6]bicyclo2.2.2]octan-2,5,7-triene) have been prepared. The molecular structure of (p-cymene)Ru(μ-Cl)2(μ-pz)Rh(tfb)] has been determined by X-ray diffraction. It consists of two moieties, (p-cymene)Ru and (tfb)Rh, triply-bridged by a pyrazolate group and two chlorine atoms.
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