| CoFeOx/MoO2准平行纳米阵列电极的析氢性能 |
| |
| 引用本文： | 李航洋,周凌,韩博鸣,谷向阳,叶晴岚,许雪棠,王凡,李斌. CoFeOx/MoO2准平行纳米阵列电极的析氢性能[J]. 无机化学学报, 2013, 29(18) |
| |
| 作者姓名： | 李航洋 周凌 韩博鸣 谷向阳 叶晴岚 许雪棠 王凡 李斌 |
| |
| 作者单位： | 广西大学化学化工学院, 广西电化学能源材料重点实验室, 南宁 530004 |
| |
| 基金项目： | 国家自然科学基金(No.22065003)和广西大学"大学生创新创业训练计划"资助项目(No.202110593183) |
| |
| 摘 要： | 利用CoFe层状双金属氢氧化物(CoFe LDH)准平行纳米片阵列作为载体前驱体,通过原位负载及煅烧方式,实现了含有氧空位的 MoO2纳米颗粒在纳米片阵列表面的生长。电化学研究结果表明,所得 CoFeOx/MoO2纳米阵列电极具有高析氢反应(HER)催化活性。该电极在10和1 000 mA·cm-2时的HER过电位分别为40和217 mV。在50 mA·cm-2的电流密度下,该电极可以稳定运行125 h。
|
| 关 键 词： | 准平行纳米阵列 MoO2 析氢性能 |
| 收稿时间： | 2022-12-18 |
| 修稿时间： | 2023-05-17 |
Hydrogen evolution performance of CoFeOx/MoO2 quasi-parallel nanoarray electrode |
| |
| LI Hang,Yang,ZHOU Ling,HAN Bo,Ming,GU Xiang,Yang,YE Qing. Hydrogen evolution performance of CoFeOx/MoO2 quasi-parallel nanoarray electrode[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(18) |
| |
| Authors: | LI Hang Yang ZHOU Ling HAN Bo Ming GU Xiang Yang YE Qing |
| |
| Affiliation: | Guangxi Key Laboratory of Electrochemical Energy Materials, School of Chemistry & Chemical Engineering, Guangxi University, Nanning 530004, China |
| |
| Abstract: | Herein, a quasi-parallel CoFe layer double hydroxide (CoFe LDH) nanosheet array was employed as precursor to regulate the deposition of MoO2 nanoparticles with abundant oxygen vacancies array by in-situ loading and calcination process. The asobtained CoFeOx/MoO2 nanoarray electrode showed the enhanced hydrogen evolution reaction (HER) activity, while it delivered the current densities of 10 and 1 000 mA·cm-2 at overpotential of 40 and 217 mV, respectively. Besides, the current density of 50 mA·cm-2 for CoFeOx/MoO2 electrode was maintained at an overpotential of 100 mV up to 125 h of operation. |
| |
| Keywords: | quasi-parallel nanosheet array molybdenum dioxide hydrogen evolution performance |
|
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
|
