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Synthesis and spectral properties of [3-(heptyloxy)phenoxy]acetic acid and its derived meso-sibstituted tetrabenzoporphyrins
Authors:N. E. Galanin  L. A. Yakubov  G. P. Shaposhnikov
Affiliation:(1) Ivanovo State Chemical Technological University, pr. F. Engel’sa 7, Ivanovo, 153000, Russia
Abstract:3-Heptyloxyphenol was obtained by reaction of resorcinol with 1-bromoheptane. Further alkylation with monochloroacetc acid resulted in the synthesis of [3-(heptyloxy)phenoxy]acetic acid. Heating of the latter with phthalimide in the presence of zinc acetate afforded zinc complexes of meso-[(3-heptyloxy)phenoxy] tetrabenzoporphyrins whose demetalization gave free porphyrin bases. Spectral properties of the synthesized compounds were studied.
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