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Platinum group metals bulk analysis in automobile catalyst recycling material by laser-induced breakdown spectroscopy
Authors:George Asimellis  Nikolaos Michos  Ioanna Fasaki  Michael Kompitsas
Institution:1. Faculty of Physics, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece;2. School of Chemical Engineering, National Technical University of Athens, 9, Iroon Polytechniou Str., Zografou, 15780 Athens, Greece;3. National Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 48, Vasileos, Konstantinou Ave., 11635 Athens, Greece
Abstract:Development and application of an in-situ applicable method to provide rapid determination of platinum group metals (platinum, palladium, and rhodium) elemental concentration in automobile catalyst scrap is reported. Application is based on laser-induced breakdown spectroscopy (LIBS). Actual automobile catalyst slurry in powder form was used to develop the application. With a method requiring approximately 1.5 min of examination per sample, calibration curves are presented with linear regression coefficients close to 0.99 and stability better than 3.0%.
Keywords:Laser-induced breakdown spectroscopy  Platinum  Palladium  Rhodium metal detection  Automobile catalyst recycling
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