| CRYSTAL AND MOLECULAR STRUCTURE OF N, N-PLATINUM-DIETHYL-DICHLORIDEDI-L-ASPARTATE |
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| 作者姓名： | 徐筱杰 周公度 唐有祺 唐雯霞 颜科 戴安邦 |
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| 作者单位： | Institute of Physical Chemistry，Peking University，Institute of Physical Chemistry，Peking University，Institute of Physical Chemistry，Peking University，Institute of Complex Chemistry，Nanjing University，Institute of Complex Chemistry，Nanjing University，Institute of Complex Chemistry，Nanjing University |
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| 摘 要： | This paper reports the crystal and molecular structure of title compound. 3978 three-dimensional independent reflections were collected by Syntex R3 four circle diffractometer. The crystal is monoclinic with space group P2_1, a=8.074(1), b=11.309(4), c=27.793(9), β=106.84°(2), Z=4. The molecular formula is Pt(C_8 H_(15)O_4N)_a Cl_2. The crystal structure was solved by Patterson method and refined by block matrix least squares refinement techniques. The final R factor is 0.039.The result of crystal structure analysis shows that Pt(Ⅱ) has a dsp~2 hybrid orbital and square coordination. Two C1 atoms are located oppositely to two diethyi-dichloride-di-L-aspartare. N atoms have sp~3 tetrahedral hybrid configurations and form the coordinate bonds with Pt(Ⅱ) atom using their lone pair electrons. By reason of molecular packing and due to the formation of inner hydrogen bonds in the complex molecule, the configuration of L-aspartic acid in the title complex is more twisted than that of L-and DL-aspartic acid
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