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Electron scattering and dissociative attachment by SF6 and its electrical-discharge by-products
Authors:H -X Wan  J H Moore  J K Olthoff  R J Van Brunt
Institution:(1) Department of Chemistry and Biochemistry, University of Maryland, 20742 College Park, Maryland;(2) National Institute of Standards and Technology, 20899 Gaithersburg, Maryland
Abstract:Discrete electron-molecule processes relevant to SF6 etching plasmas are examined. Absolute, total scattering cross sections for 0.2–12-eV electrons on SF6, SO2, SOF2, SO2F2, SOF4, and SF4, as well as cross sections for negative-ion formation by attachment of electrons, have been measured. These are used to calculate dissociative-attachment rate coefficients as a function ofE/N for SF6 by-products in SF6.
Keywords:Attachment rates  cross section  dissociative attachment  electron scattering  SF6  SF4  SO2  SOF2  SOF4  SO2F2
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