Enthalpies of elementary chain propagation steps in the oxidation of organic compounds |
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| Authors: | I. M. Borisov D. A. Mikhaylov S. L. Khursan |
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| Affiliation: | (1) Bashkir State University, 450074 Ufa, Russia;(2) Institute of Organic Chemistry, Russian Academy of Sciences, 450054 Ufa, Ufa Scientific Center, Russia |
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| Abstract: | A calculation of the enthalpies of elementary steps of the intra- and intermolecular chain propagation for model oxidation reactions of ethers, esters, ketones and hydrocarbons has been carried out. The heats of the intermolecular and intramolecular transfer of free valence with participation of peroxy radicals and C−H bond of the oxygen-containing compounds are shown to be comparable. |
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| Keywords: | Enthalpy chain propagation oxidation |
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