Boundary conditions in the theory of the relaxation field |
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Authors: | Raymond M. Fuoss |
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Affiliation: | (1) Sterling Chemistry Laboratory, Yale University, 06520 New Haven, Connecticut |
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Abstract: | The perturbationfji' generated by an external field in the distribution function is derived by integration of the Onsager-Fuoss equation of continuity. The solution isfji'(r)=C(I+Ah1+Bh2) whereCI is a particular integral andh1 andh2 are solutions of the homogeneous equation. The physical significance of the boundary conditions which evaluate the constantsA andB is discussed. It is then shown that the conditionfji'( ) 0 requiresB=0 and that the condition lim(fji'/n2) 0 at zero concentration is satisfied if and only ifA=–1. |
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Keywords: | Boundary conditions relaxation field theory |
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