Study of contamination sources in the process of cryogenic grinding

The study of contamination effect during cryogenic grinding of pure cellulose was carried out. The optimisation of important parameters of the grinding process (pre-cooling time, grinding time, cooling time and number of cycles) was performed and the different sources of a possible contamination of samples (earlier processed sample, metal parts of grinding tool) were evaluated. The results of ICP-oa-TOF MS analysis after microwave digestion of cellulose samples were used in this study. Significant contamination of cellulose samples by Fe at the level 130 microg kg(-1) caused by wearing of steel stoppers and an impact bar was detected. Cross-contamination by Fe, Cr, Mn and Cu at the level 400, 200, 200 and 2100 microg kg(-1), respectively was caused by previous grinding of electro-waste sample. This cross-contamination was possible to be avoided by changing of a polycarbonate part of a grinding vessel.