A tetrathiafulvalene–perylene diimide conjugate prepared via click chemistry |
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| Authors: | Katrine Qvortrup Michael xman Petersen Tue Hassenkam Mogens Brndsted Nielsen |
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| Institution: | aDepartment of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark |
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| Abstract: | A new tetrathiafulvalene (TTF)–perylene diimide (PDI) conjugate is prepared from an azide-functionalized TTF and an acetylenic PDI employing a Cu(I)-catalyzed Huisgen-Meldal-Sharpless reaction (‘click chemistry’). Thus, the TTF donor and PDI acceptor units are linked together by a 1,2,3-triazole unit. The molecules are found to assemble on a mica surface, forming fibrilar structures. |
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| Keywords: | Alkynes Click chemistry Perylene diimide Tetrathiafulvalene |
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