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Silylated iminophosphonates: Novel reactive synthons for the preparation of fluorinated aminophosphonates and aminophosphonic acids |
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| Authors: | Yuliya V Rassukana Oleg V Stanko Ivanna P Yelenich Petro P Onys&#x;ko |
| Institution: | 1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmans’ka str., Kyiv 02660, Ukraine;2. Department of Organic Chemistry, National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37, Prospect Peremogy, Kyiv 03056, Ukraine |
| Abstract: | A convenient synthetic approach towards previously unknown N- and N,O-silylated α-iminophosphonates bearing fluoroalkyl groups at the imine C atom was developed. The synthetic potential of the compounds was demonstrated by their easy functionalization and the straightforward preparation of biorelevant aminophosphonates and free aminophosphonic acids with heterocyclic residues in the α-position. |
| Keywords: | Iminophosphonates Aminophosphonates Aminophosphonic acids Trimethylsilyl Fluoroalkyl |
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