An oxidovanadium(IV) complex having a perrhenato ligand: An efficient catalyst for aerobic oxidation reactions of benzylic and propargylic alcohols |
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| Authors: | Daiki Kobayashi Shintaro Kodama Youichi Ishii |
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| Institution: | Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan |
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| Abstract: | An oxidovanadium(IV) complex having a perrhenato ligand VO(ReO4)(4,4′-tBubpy)2]0.25SO4·0.5ReO4] (4,4′-tBubpy = 4,4′-di-tert-butyl-2,2′-bipyridine) efficiently catalyzes not only dehydrogenative oxidation of benzylic and propargylic mono-alcohols but also oxidative C | |
| Keywords: | Oxidation reactions Oxidovanadium complexes Perrhenate ions Benzylic alcohols Molecular oxygen |
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