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Enantioselective total synthesis of cis-(+)- and trans-(+)-disparlure |
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| Authors: | Yuvraj Garg Anand Kumar Tiwari Satyendra Kumar Pandey |
| Institution: | School of Chemistry and Biochemistry, Thapar University, Patiala 147001, India |
| Abstract: | An expedient enantioselective synthetic approach for the gypsy moth sex-attractant pheromone cis-(+)-1 and trans-(+)-disparlure 2 is described employing the optimized combination of organocatalytic MacMillan’s self aldol reaction, Wittig olefination, regioselective ring opening of an epoxide and Mitsunobu esterification reactions as key steps. |
| Keywords: | Sex-attractant pheromone Disparlure MacMillan’s self aldol reaction Wittig olefination Mitsunobu esterification |
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