|
|||||
|
|
The first diastereoselective nitroaziridination of N-tosylaldimines with 1-bromonitroalkanes |
|
| Authors: | Lal Dhar S. Yadav Garima Ritu Kapoor |
| Affiliation: | Green Synthesis Lab, Department of Chemistry, University of Allahabad, Allahabad 211 002, India |
| Abstract: | The first expeditious nitroaziridination of N-tosylaldimines is reported. The protocol involves operationally simple catalyst-free reaction of N-tosylaldimines, 1-bromonitroalkanes and NaOAc to afford 2-nitro-1-tosylaziridines in excellent yields with high Z-diastereoselectivity in a one-pot procedure under ambient conditions. |
| Keywords: | Aziridines N-tosylaldimines 1-Bromonitroalkanes Stereoselective synthesis Nucleophilic substitution Cyclization reaction |
| 本文献已被 ScienceDirect 等数据库收录！ | |