Novel optically active organometallic derivatives of fullerenes with non-central types of chirality in addends: synthetic and CD studies期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Novel optically active organometallic derivatives of fullerenes with non-central types of chirality in addends: synthetic and CD studies

Authors:	Viatcheslav I. Sokolov Vasily V. Bashilov Fedor M. Dolgushin Natalya V. Abramova Kyrill K. Babievsky Allan G. Ginzburg Pavel V. Petrovskii

Affiliation:	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28, Vavilov Street, 119991 Moscow, Russian Federation

Abstract:	Palladium and platinum complexes of C₆₀ and C₇₀ possessing the enantiomeric ligand (−)-Bitianp with axial chirality and a pyrrolidino[60]fullerene bearing a planar chiral organometallic π-complex group in the heterocyclic ring have been synthesized and their CD spectra recorded.

Keywords:	Fullerenes Organometallic derivatives Palladium complex Platinum complex Pyrrolidino[60]fullerenes Dicymantrenyl Optical activity Axial chirality Planar chirality Circular dichroism Cotton effects
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