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Iodine-catalyzed intermolecular hydroamination of vinyl arenes
Authors:JS Yadav  BV Subba Reddy  T Srinivasa Rao  B Bala M Krishna
Institution:Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:The vinyl arenes undergo smooth hydroamination with sulfonamides in the presence of 10 mol % of iodine to furnish tosyl and mesyl-protected secondary amines in excellent yields in short reaction times. The use of inexpensive and readily available molecular iodine makes this method quite simple, more convenient, and practical.
Keywords:Hydroamination  Vinyl arenes  Molecular iodine  Sulfonamides
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