Microwave-assisted, solvent-free oxidative cleavage of α-hydroxyketones |
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| Authors: | Ignacio Carrera |
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| Institution: | Departamento de Química Orgánica, Facultad de Química, Universidad de la República. General Flores 2124, C.P. 11800, Montevideo, Uruguay |
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| Abstract: | The oxidative C-C cleavage of α-hydroxy ketones was found to proceed smoothly in solvent-free, silica-supported sodium metaperiodate, under microwave irradiation. This provides a useful and green synthetic procedure to form the corresponding carboxylic acid and aldehyde in good yields, avoiding the solubility problems of the sodium metaperiodate in organic solvents. |
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| Keywords: | Green-chemistry α-Hydroxyketones Sodium metaperiodate Microwave-assisted oxidation |
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