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An inexpensive cyclodiphosphazane as an efficient ligand for the palladium-catalyzed amination of aryl bromides and chlorides
Authors:R. Rama Suresh
Affiliation:School of Chemistry, University of Hyderabad, Hyderabad 500 046, AP, India
Abstract:An economic and novel ligand, cyclodiphosphazane [ClPN(t-Bu)]2 (1), was introduced in the palladium-catalyzed amination of unactivated aryl halides. The catalyst allows for the amination of aryl chlorides and bromides with secondary cyclic amines and anilines in good yields.
Keywords:Aryl chlorides   C-N coupling   Amination   Palladium catalysis
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