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The theory of a vibrating-rod densimeter
Authors:T Retsina  S M Richardson and W A Wakeham
Institution:(1) Department of Chemical Engineering and Chemical Technology, Imperial College, Prince Consort Road, SW7 2BY London, England, UK
Abstract:The paper presents a theory of a device for the accurate determination of the density of fluids over a wide range of thermodynamic states. The instrument is based upon the measurement of the characteristics of the resonance of a circular section tube, or rod, performing steady, transverse oscillations in the fluid. The theory developed accounts for the fluid motion external to the rod as well as the mechanical motion of the rod and is valid over a defined range of conditions. A complete set of working equations and corrections is obtained for the instrument which, together with the limits of the validity of the theory, prescribe the parameters of a practical design capable of high accuracy.Nomenclature A, B, C, D constants in equation (60) - A j , B j constants in equation (18) - a j + , a j wavenumbers given by equation (19) - C f drag coefficient defined in equation (64) - C f /0 , C f /1 components of C f in series expansion in powers of epsi - c speed of sound - D b drag force of fluid b - D 0 coefficient of internal damping - E extensional modulus - 
$$F,\tilde F$$
force per unit length - F j + , F j constants in equation (24) - f, g functions of sgr defined in equations (56) - G modulus of rigidity - I second moment of area - K constant in equation (90) - k, kprime constants defined in equations (9) - L half-length of oscillator - Ma Mach number - m a mass per unit length of fluid a - m b added mass per unit length of fluid b - m s mass per unit length of solid - n j eigenvalue defined in equation (17) - P power (energy per cycle) - P a , P b power in fluids a and b - p pressure - R radius of rod or outer radius of tube - R c radius of container - R i inner radius of tube - r radial coordinate - T tension - T visc temperature rise due to heat generation by viscous dissipation - t time - v r , v theta radial and angular velocity components - y lateral displacement - z axial coordinate - agr dimensionless tension - beta a dimensionless mass of fluid a - beta b dimensionless added mass of fluid b - betaprime b dimensionless drag of fluid b - gamma dimensionless parameter associated with lambda - Delta0 dimensionless coefficient of internal damping - 
$$\Delta \tilde \omega $$
dimensionless half-width of resonance curve - 
$$\Delta \tilde \omega _r $$
dimensionless frequency difference defined in equation (87) - delta spatial resolution of amplitude - deltaR, deltamgr, deltargr, deltargr s , deltaohgr increments in R, mgr, rgr, rgr s , ohgr - epsi dimensionless amplitude of oscillation - zeta dimensionless axial coordinate - eegr ratio of 
$$\tilde \omega _0 $$
to 
$$\tilde \omega _r $$
- eegr a , eegr b ratios of 
$$\tilde \omega _0 $$
to 
$$\tilde \omega _r $$
for fluids a and b - theta angular coordinate - lambda parameter arising from distortion of initially plane cross-sections - lambda f thermal conductivity of fluid - Lambda dimensionless parameter associated with lambda - mgr viscosity of fluid - mgr a , mgr b viscosity of fluids a and b - xgr dimensionless displacement - xgr j jth component of xgr - rgr density of fluid - rgr a , rgr b density of fluids a and b - rgr s density of tube or rod material - rgrprime density of fluid calculated on assumption that sgr* rarr infin - sgr dimensionless radial coordinate - sgr* dimensionless radius of container - 
$$\tau ,\tilde \tau $$
dimensionless times - tau rr taurr, taurtheta radial normal and shear stress components - phgr spatial component of xgr defined in equation (13) - phgr j jth component of phgr - PHgr dimensionless streamfunction - PHgr0, PHgr1 components of PHgr in series expansion in powers of epsi - chi phase angle - chi r phase difference - chi ra , chi rb phase difference for fluids a and b - PSgr streamfunction - PSgr j jth component defined in equation (22) - OHgr dimensionless frequency (based on rgr) - OHgr a , OHgr b dimensionless frequency in fluids a and b - OHgr s dimensionless frequency (based on rgr s ) - ohgr angular frequency - ohgr 0 resonant frequency in absence of fluid and internal damping - ohgr r resonant frequency in absence of internal fluid - ohgr ra , ohgr rb resonant frequencies in fluids a and b - 
$$\tilde \omega $$
dimensionless frequency - 
$$\tilde \omega _r $$
dimensionless frequency when beta a vanishes - 
$$\tilde \omega _{ra} ,\tilde \omega _{rb} $$
dimensionless frequencies when beta a vanishes in fluids a and b - 
$$\tilde \omega _0 $$
dimensionless resonant frequency when beta a , betab, betaprimeb and Delta0 vanish - 
$$\tilde \omega _1 $$
dimensionless resonant frequency when beta a , betab and betaprime b vanish - 
$$\tilde \omega _2 $$
dimensionless resonant frequency when beta b and betaprime b vanish - 
$$\tilde \omega _ +  ,\tilde \omega _ -  $$
dimensionless frequencies at which amplitude is half that at resonance
Keywords:
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