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The photoionisation of propargylene and diazopropyne
Authors:Steinbauer Michael  Lang Melanie  Fischer Ingo  de Miranda Bárbara K Cunha  Romanzin Claire  Alcaraz Christian
Affiliation:Institute of Physical and Theoretical Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany.
Abstract:The photoionisation of the C(3)H(2) isomer propargylene was studied using synchrotron radiation and coincidence techniques. An adiabatic ionisation energy (IE(ad)) of 8.99 ± 0.02 eV was determined. The precursor diazopropyne was investigated as well. Ionisation and appearance energies were measured.
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