Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels |
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| Authors: | Gu Ja-Min Kim Wan-Seok Huh Seong |
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| Institution: | Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, 449-791, Korea. |
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| Abstract: | Lewis basic DABCO-functionalized 3D-like metal-organic framework, Zn-MOF, catalyzes nitroaldol (Henry) reaction of 4-nitrobenzaldehyde with nitroalkanes in a size-dependent manner. Small nitroalkanes give rise to higher conversion than larger ones. This MOF-based heterogeneous catalyst is very robust and can be recycled several times without losing its activity. |
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