Effect of the nature and concentration of the zeolite Y cation on the hydrogenation and isomerization of 2-methyl-2-butene |
| |
Authors: | Kh M Minachev V V Kharlamov V I Garanin D B Tagiev |
| |
Institution: | (1) Department of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou, 310027, China; |
| |
Abstract: | 1. |
Up to a certain point (55%), decationization of NaY zeolites reduces the activity of the zeolites in catalyzing the hydrogenation of 2-methyl-2-butene. Further decationization had no effect on the yield of saturated hydrocarbons.
| 2. |
Plotted as a function of the cation's electrostatic potential, the activity of MNaY zeolites in catalyzing the hydrogenation of 2-methyl-2-butene passes through a maximum. Minimum activity was observed with the NdNaY zeolite.
| 3. |
Experiments in an atmosphere of helium showed that saturated hydrocarbons, resulting from hydrogen redistribution, are frequently formed in the course of reactions on decationized and polyvalent cationic forms of the Y zeolite.
|
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|