CHLOROMETHYLATION OF POLYMERS MADE FROM TECHNICAL DIVINYLBENZENE AND PROPERTY OF THE CHLOROMETHYLATED POLYMERS |
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| Authors: | Shi Rongfu Xu Mancai SHI Zuoqing Wang Chunhong FAN YunGe Feng Junqian HE Binglin |
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| Affiliation: | 1. The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation,Institute of Polymer Chemistry, Nankai University, Tianjin 300071, P R. China
2. The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation,Institute of Polymer Chemistry, Nankai University, Tianjin 300071, P R. China;Department of Chemistry, Hunan Normal University, Changsha 410081, P. R. China |
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| Abstract: | The goal this paper was to reveal the feasibility of chloromethylation of polymers made from technical divinylbenzene so as to introduce functional groups into polymeric adsorbents.Forthis study,the factors,that effect the chloromethylation reaction,such as the pore structure of the polymer,the ratio of the reactants to catalyst,the reaction temperature and reaction time and so on were investigated.and the pore structure and property of the chloromethylated polymers were studied.The results showed that polymers of technical divinylbenzene could be chloromethylated successfully,and the adsorptive property of the chloromethylated resin was different from that of the initial resin. |
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| Keywords: | Chloromethylated polymer Polydivinylbenzene Adsorption |
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