Observation of laser speckle effects and nonclassical kinetics in an elementary chemical reaction |
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Authors: | Monson E Kopelman R |
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Institution: | Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA. |
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Abstract: | An experimental demonstration is provided for memory-based, nonclassical reaction kinetics in a homogeneous system with an elementary reaction, A+B-->C. A new reaction-kinetics regime is observed which is a direct consequence of speckles in the laser beam. However, in spite of the nonrandom, speckled initial distribution of reactant B, the long-time regime gives the first experimental demonstration of the asymptotic self-segregation ("Zeldovich") effect. Monte Carlo simulation results are consistent with the experiments. |
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