Detection of chemical warfare simulants by phosphorylation of a coumarin oximate |
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| Authors: | Wallace Karl J Fagbemi Ruth I Folmer-Andersen Frantz J Morey Jeroni Lynth Vincent M Anslyn Eric V |
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| Institution: | Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX, USA. |
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| Abstract: | The detection of chemical warfare simulants is attained by the PET mechanism that gives an "off-on" fluorescent response with a half-life of approximately 50 ms upon phosphorylation of a reactive oximate functionality; the X-ray crystal structure of the oximate was also obtained and is discussed. |
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