| 异戊二烯和四氟乙烯-丙烯共聚物的光化学接枝反应 |
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| 引用本文： | 黄骏廉,吴海新. 异戊二烯和四氟乙烯-丙烯共聚物的光化学接枝反应[J]. 影像科学与光化学, 1990, 8(3): 186-191. DOI: 10.7517/j.issn.1674-0475.1990.03.186 |
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| 作者姓名： | 黄骏廉 吴海新 |
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| 作者单位： | 复旦大学材料科学研究所, 上海 200433 |
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| 摘 要： | 在紫外光作用下,二苯甲酮、蒽醌和安息香能通过夺氢反应使异戊二烯在四氟乙烯-丙烯共聚物中接枝,接枝反应按三重态自由基引发机理进行,接枝率随光照时间的增长而增加,但不会超过40%。和异戊二烯的自由基聚合反应不一样,接枝物中聚异戊二烯接枝链的微结构以3,4-和1,2-聚合为主,而前者以1,4-聚合为主。Ce+4及Fe+2-H2O2等氧化还原体系对该接枝反应不产生作用.极性溶剂四氢呋喃的加入,对接枝链微结构的影响很小。
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| 关 键 词： | 异戊二烯 光化学接枝 四氟乙烯-丙烯共聚物 |
| 收稿时间： | 1988-11-07 |
THE PHOTOCHEMICAL GRAFT COPOLYMERIZATION OF ISOPRENE TETRAFLUOROETHYLENE-CO-PROPYLENE |
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| HUANG JUN-LIAN,WU HAI-XING. THE PHOTOCHEMICAL GRAFT COPOLYMERIZATION OF ISOPRENE TETRAFLUOROETHYLENE-CO-PROPYLENE[J]. Imaging Science and Photochemistry, 1990, 8(3): 186-191. DOI: 10.7517/j.issn.1674-0475.1990.03.186 |
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| Authors: | HUANG JUN-LIAN WU HAI-XING |
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| Affiliation: | Institute of Material Science, Fudan University, Shanghai 200453, P. R. China |
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| Abstract: | The graft copolymerization of isoprene on the surface of tetrafluoroethylene-co-propylene-could take place by abstracting the hydrogen atom from propylene in copolymer by benzophene anthroquinone and beizoin at UV irradiating- The graft reaction carries out on the mechanism of triplet radicals.The graft efficiency increases with the lengthening of irradiation time,but no more than 40%.The microstructure of grafting chain of polyisoprene is mainly composed of 3,4- and 1,2-polymerization of isoprene.And the polymerisoprene made by radical polymerization consisted of 1,4-polymerization of isoprene essentially.The redox initiation system used for this graft copolymerization,such as Ce+4 or Fe+2-H2O2 is ineffective.The polar solvent,for example THF,has little influence on the microstructure-of grafting chain of polyisoprene. |
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| Keywords: | isoprene photochemical graft copolymer of tetrafluoroethylene and propylene |
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