Organocatalysis in water at room temperature with in-flask catalyst recycling |
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| Authors: | Lipshutz Bruce H Ghorai Subir |
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| Affiliation: | Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA. lipshutz@chem.ucsb.edu |
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| Abstract: | A new designer surfactant is described containing a covalently bound organocatalyst, proline. This species is water-soluble and, via spontaneous nanomicelle formation, catalyzes aldol reactions on water-soluble or -insoluble substrates in water as the only medium. Recycling the catalyst is trivial, as the amphiphile/catalyst remains in the aqueous phase in the flask. |
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