Catalytic Addition of Simple Alkenes to Carbonyl Compounds Using Group 10 Metals |
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Authors: | Ho Chun-Yu Schleicher Kristin D Jamison Timothy F |
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Affiliation: | Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, NT, Hong Kong SAR (P.R. China). |
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Abstract: | Recent advances using nickel complexes in the activation of unactivated monosubstituted olefins for catalytic intermolecular carbon-carbon bond-forming reactions with carbonyl compounds, such as simple aldehydes, isocyanates, and conjugated aldehydes and ketones, are discussed. In these reactions, the olefins function as vinyl- and allylmetal equivalents, providing a new strategy for organic synthesis. Current limitations and the outlook for this new strategy are also discussed. |
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