The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts |
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| Authors: | Singh Bindra Gurmeet Schulz Martin Paul Avishek Soman Suraj Groarke Robert Inglis Jane Pryce Mary T Browne Wesley R Rau Sven Maclean Brian J Vos Johannes G |
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| Affiliation: | SRC for Solar Energy Conversion, School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9, Dublin, Ireland. |
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| Abstract: | A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not. |
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