Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C-N coupling |
| |
| Authors: | Kanoo Prakash Haldar Ritesh Cyriac Soumya T Maji Tapas Kumar |
| |
| Institution: | Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India. |
| |
| Abstract: | Metal mediated in situ C-N coupling between 4,4'-azobipyridine and disodium-trans-glutaconate at room temperature has formed a new multifunctional linker Z-dhpe which subsequently self-assembles with Zn(II) or Cd(II) resulting in a chiral or an achiral metal-organic framework, respectively, depending on its different coordination modes. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
