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Synthesis of Fullerene-Acrylamide Copolymer Nanoball and Its Lubrication Properties
引用本文:江贵长 官文超 郑启新. Synthesis of Fullerene-Acrylamide Copolymer Nanoball and Its Lubrication Properties[J]. 中国化学, 2004, 22(8): 877-881. DOI: 10.1002/cjoc.20040220824
作者姓名:江贵长 官文超 郑启新
作者单位:DepartmentofChemistry,HuazhongUniversityofScienceandTechnology,Wuhan,Hubei430074,China
基金项目:Project supported by the National Natural Science Foundation of China (No. 20074012) and Anhui Provincial Universities Natural Science Founda-tion (No. 2002kj290).
摘    要:A novel fuUerene-acrylamide copolymer was synthesized via radical polymerization. It is soluble in polar solvents such as water, dimethyl sulfoxide etc. The product was characterized by FTIR, UV-Vis and GPC. TEM analysis shows that the average particle diameter is about 46 nm. Four-ball tests show that the addition of a certain concentration of the fullerene copolymer to base stock (2 wt% triethanolamine and 0.5 wt% OPZ aqueous solution) can effectively raise the load-carrying capacity (PB value) and the antiwear ability. SEM analysis shows that the addition results in reducing diameter of wear scar and decreasing wear.

关 键 词:合成 球壳状碳分子-丙烯酰胺共聚物纳米球 润滑性质 水溶性

Synthesis of Fullerene-Acrylamide Copolymer Nanoball and Its Lubrication Properties
JIANG,Gui-Chang. Synthesis of Fullerene-Acrylamide Copolymer Nanoball and Its Lubrication Properties[J]. Chinese Journal of Chemistry, 2004, 22(8): 877-881. DOI: 10.1002/cjoc.20040220824
Authors:JIANG  Gui-Chang
Affiliation:JIANG,Gui-Chang*,
Abstract:A novel fullerene-acrylamide copolymer was synthesized via radical polymerization. It is soluble in polar sol- vents such as water, dimethyl sulfoxide etc. The product was characterized by FTIR, UV-Vis and GPC. TEM analy- sis shows that the average particle diameter is about 46 nm. Four-ball tests show that the addition of a certain con- centration of the fullerene copolymer to base stock (2 wt% triethanolamine and 0.5 wt% OPZ aqueous solution) can effectively raise the load-carrying capacity (PB value) and the antiwear ability. SEM analysis shows that the addition results in reducing diameter of wear scar and decreasing wear.
Keywords:fullerene-acrylamide copolymer   water solubility   lubrication property   nanoball
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