Charge-transfer reactions in clusters excited with synchrotron radiation |
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| Authors: | L. Museur A.V. Kanaev M.C. Castex L. Moussavizadeh R. von Pietrowski T. Möller |
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| Affiliation: | (1) The Institute of Analytical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P.R. China; |
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| Abstract: | Charge-transfer reactions are observed in a photoluminescence study of NF3rm NF_3-doped free krypton clusters. They show up in emissions from Kr+F-rm Kr^{+}F^{-}free excimers ejected from the clusters, and from excited Kr2+F-rm Kr_2^{+}F^{-}and Kr2+(NF3)m-{rm Kr}_2^{+}({rm NF}_3)_m^{-} (m 3(mgeq 1) solvated in the clusters. The results show that reaction dynamics in clusters differs considerably from that in the gas and solid phases. |
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