Hydrocarboxylation of polybutylene on palladium complex catalysts |
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| Authors: | A. L. Lapidus S. Ya. Grobovenko A. V. Goryachevskaya E. L. Berman A. D. Kagarlitskii |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow;(2) Institute of Organic Synthesis and Coal Chemistry, Academy of Sciences of the Kazakh SSR, Karaganda |
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| Abstract: | Conclusions The introduction of carboxyl groups into up to 60% of the double bonds in a polybutadiene sample is possible at 90–170°C and 2.0–14.0 MPa in the presence of PdCl2(PPh3)2 and added PPh3.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1390–1392, June, 1989.The authors express their gratitude to S. D. Sominskii for assistance in carrying out the IR studies. |
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