Application of phosphine-oxazoline ligands in Ir-catalyzed asymmetric hydrogenation of acyclic aromatic N-arylimines |
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Authors: | Trifonova Anna Diesen Jarle S Chapman Christopher J Andersson Pher G |
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Affiliation: | Department of Chemistry, Organic Chemistry, Uppsala University, Box 599, SE-75124 Uppsala, Sweden. |
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Abstract: | [reaction: see text] A new class of chiral phosphine-oxazoline ligands have been developed. Chiral Ir complexes prepared from these ligands induced high enantioselectivities (66-90% ee) when applied to the asymmetric hydrogenation of acyclic aromatic N-arylimines. |
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