Synthesis,structures and properties ofN-(trihalogermylmethyl)-substituted amides,lactams and imides,the derivatives of the five-coordinate germanium |
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Authors: | T K Gar O A Dombrova D A Ivashchenko V F Mironov |
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Institution: | (1) State Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Enthuziastov, 111123 Moscow, Russian Federation |
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Abstract: | The formation of trichlorogermyl-substituted amides, lactams, and imides occurs when 2Et2O·HGeCl3 is condensed with compounds possessing the -NCH2Cl fragment and equally well when HGeCl3 interacts with compounds containing -NCH2OH and-NCH2OSiMe3 groups. In some cases, the use of the latter is more advantageous from the preparative point of view. In compounds thus obtained,
the germanium is five-coordinate due to the coordination
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Deceased August 13, 1993.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1793–1799, October, 1993. |
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Keywords: | N-(trichlorogermylmethyl)-substituted amides lactams and imides synthesis structure |
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