Triphenylbismuth diacylates as novel reagents for fine organic synthesis |
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| Authors: | V A Dodonov A V Gushchin |
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| Institution: | (1) N. I. Lobachevsky Nyzhnii Novgorod State University, 23 prosp. Gagarina, 603600 Nyzhnii Novgorod, Russian Federation |
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| Abstract: | Triphenylbismuth diacylates, Ph3Bi(O2CR)2 (R = Me, Et, Ph, CF3, CH=CH2), are novel effective reagents for fine organic synthesis. They oxidize primary and secondary alcohols and di-tert-glycols under mild conditions to form the corresponding carbonyl compounds in high yields;O- andN-phenylate alcohols, enols, and amines; andO- ando-C-phenylate phenols.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2043–2047, December, 1993. |
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| Keywords: | triphenylbismuth diacylates oxidation phenylation alcohols diols enols phenols amines aminoesters |
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